Pipe thread lubricant



mesne Ell? F seems; one "i noouresur Herschel -.G.

h, Swortore, li o... essignon m m w; to Gull on (lorporstlon,

lav llttsburgh, Pet, s. corporation oi Pcylvonis No Brewing. Application March 1d, i932, Serial No. 715,555

it claims.

This invention. relates to pipe thread lubricants and it comprises e composition of matter useful for application to pipe threads and the like to prevent seizing, gelling and stripping, the said fully hereinafter set forth and as claimed.

' tlnct tendency to freeze.

In the construction of pipe lines, in the oil and natural gas industries for example, a. large number of relatively dlficult problems have been encountered. One such problem which has caused considerable dlmculty is encountered especially in the uncoupling of large sized threaded pipe joints. Such joints, after having been united for e short time, tend to freeze or grip tightly, the threads seize and stripping usually results. It has been recognized for some time that a. speoiei type of lubricant is required for such threaded joints and s. considerable number have been proposed in the art.

Most oi the pipe thread lubricants heretofore proposed hove included one or more powdered solids dispersed in various types of lubricating noses. These prior lubricants have not, however,

v solved the difiaculties involved. Pipe Joints made up with these lubricants after 2. time have a. dis-- They usually have to be hammered prior to uncoupling. At times stripping is caused. Upon examination of the threads otter separation of the joint, it is seen that there is en sccumuletion of the powdered solid st the case of the threads. The surfaces of the threads have s. bright metallic appearance showing that these portions have not been sctisisctorily lubricated and tiist there has been a. gripping action between the two motel surfaces.

K have discovered that the freezing of pipe thread joints can be substantially completely avoided by introducing, into s pipe thread lubricent containing a. grease or petroletum base and s lubricating metellic powder, a. component capable oi importing extreme pressure lubricating characteristics or high iced carrying properties; this component usually comprising a. chlorinated hydrocarbon or e constituent containing sulfur, such as sidiur itself or e sulfudsed oil.

when an ingredient imparting extreme pressure characteristics is added to e lubricant contelnlng s. lubricsting metallic wwder and o. greese or petroletum base, set. with (Cl. fil -9) my invention, there appears to be a. distinct cooperation between the various constituents. Threaded joints made up with such e lubricant show almost no tendency to freeze. There is out small tendency for the lubricant to squeeze out under pressure. The joints separate with a smooth and even tightness. Upon excminetlon of a separated joint it is found that the lubricant is spread evenly, without appreciable accumulation at the base of the threads. faces of the threads-present a. dull appearance indicating that these surfaces have been covered with lubricant and have not been in metallic contact with the adjoining surfaces of the threads of the other fitting. A microscopic examination of these surfaces shows that all constituents of the lubricant are present to some extent in a film coating which covers the surfaces of the threads. There is apparently no appreciable segregation of the constituents of my lubricant in this film.

I have tested a large number of materials possessing extreme pressure characteristics and have found that all are advantageous constituents of pipe tluesid lubricants. sulfur, the halogens, sulfur-oxygen and sulfurchlorlne compounds, sullurized oils, such as sul furized sperm oil, various halogenated hydrocarbons such as chlorinated oils and waxes, hexachlorethene, chlorinated nnphthalene, lard oil treated with sulphur chloride, etc. All chlorinoted hydrocarbons characterized by low volatility appear to be useful in my invention. Finely ground sulfur is one of the best materials which I have tested.

0f the lubricating metallic powders useful in my composition, zinc and aluminum appear to be the best. Graphite is sometimes useful in these compositions in addition to a. powdered metal.

In my pipe thread lubricant it is sometimes advantageous to add a hygroscopic agent, such as glycerine or glycol, in order to prevent drying or coking.

While metal soap greases, such as the lubriouting greases used in grease cups and the like, are most advantageous in my composition, this lubricating loose my be replaced by petrolstum, for example. I usually employ an alkaline earth soap grease but other metal soap greases, such as aluminum, are also useful.

A viscosity reducing oil is also added to my composition in the proportion required to produce the desired consistency. I usually use a. light peremn oil for this purpose.

Moreover the sur T These materials include saponiiication being conducted under steam pressure and in the presence of a small proportion of pale paraflln oil. Upon release of the steam pressure an additional quantity of the paramn oil was worked into the grease and finally zinc dust, powdered sulfur and graphite were intermixed while the composition was still hot. A filnal adjustment oi the consistency was made by adding a further amount of parafiin oil andthe grease was finally drawn oil and packaged.

In the following table three typical formulae are given within the purview of my invention. These were compounded by the method indicated above.

Grease Make-up in percent by weight A fi "6 150 vis. (100 F.)

Parafin oil Calcium tallow oil scap..... Zinc dust Powdered sullune Melting point of finished grease in F. by

Hawx urst Because of the useof tallow in manufacture of the soap, a small amount of glycerine, as well as a trace of water, was present in the product.

It is possible to vary the proportions of the various ingredients employed in my composition to a considerable extent. Those indicated in the above table are merely illustrative. For example the metal powder in the composition may range from about per centto 50 per cent by weight. .The proportion of thinning oil may vary accord= ing to the consistency desired in the finished product. The sulfur-carrying ingredient may vary from as low as 1 percent in the case of sulfur, up to about per cent in the case of sulfurized sperm oil, while the graphite may be used in proportions up to per cent, or higher. As stated above many of these constituents may be replaced by equivalent materials performing the same function.

I usually prefer to make up my lubricant in paste form to about the consistency of a lubricating grease of medium or soft type. It is possible of course to dissolve my composition in a volatile solvent or to melt the same for convenience in application. When applied in this form the composition should be well stirred to keep the solid materials in suspension.-

When I use the term lubricating metallic powder, I mean thereby a metallic powder What I claim ia:==

i. As an improved lubricating grease, suitable for lubricating threaded pipe joints and the like g tight, non-freezing joints, a pipe thread lubricant comprising a major amount of a metal soap grease as the lubricating base and minor amounts of a lubricating metallic powder and a sulfur-containing ingredient imparting extreme pressure characteristics to said composition.

2. The lubricant of claim 1 wherein the metallic powder is zinc powder.

3. The lubricant of claim 1 wherein a small amount of a hygroscopic agent is present.

4. A pipe-thread lubricant comprising a major amount of an alkaline earth metal soap grease as the lubricating base, and minor amounts of a lubricating metallic powder and a sulfur-containing ingredient imparting extreme pressure characteristics selected from a class consisting of sulfur itself and sulfurized oils.

5. The lubricant of claim 4 wherein the sulfurcontaining ingredient is sulfur.

6. The lubricant of claim 'wherein a small amount of a hygroscopic agent is present.

'7. A pipe-thread lubricant comprising a calcium soap grease as the lubricating base, and minor amounts of a lubricating metallic powder, graphite and a component containing sulfur and capable of imparting extreme pressure lubricating characteristics to said lubricant.

8. A pipe thread lubricant capable of making tight, non-freezing joints, said lubricant comprising a grease base of petroleum oil and metal soap, a lubricating metallic powder and a constituent imparting extreme pressure characteristics containing sulfur.

9. A pipe-thread lubricant comprising amorphous graphite, sulfur, zinc dust and calcium tal low oil soap grease.

10. A pipe-thread lubricant comprising amorphous graphite, sulfur, zinc dust and a metal soap grease base.

11. A pipe-thread lubricant comprising calcium tallow oil soap grease, a thinning oil, amorphous graphite and a sulfur-containing constituent imparting extreme pressure characteristics.

12. A pipe thread lubricant capable of making tight, non-freezing joints, said lubricant comprising a grease base of petroleum oil, and metal soap, a lubricating metallic powder, a sulfur-contain ing constituent imparting extreme pressure characteristics and a hygroscopic agent.

um tallow oil soap reduced in viscosity by con taining paramn oil, abgut 20 per cent zinc dust,

about 2 per cent sulfur, about 2 per cent colloidal graphite and about 1 per cent glycerine.

I 51'? Y" Yr? 

